2-(4-Fluorophenyl)-5-iodo-3-isopropylsulfonyl-1-benzofuran
نویسندگان
چکیده
There are two symmetry-independent mol-ecules, A and B, in the asymmetric unit of the title compound, C(17)H(14)FIO(3)S. The dihedral angle formed by the 4-fluoro-phenyl ring and the mean plane [r.m.s. deviation = 0.013 (2) Å in mol-ecule A and 0.016 (2) Å in mol-ecule B] of the benzofuran fragment is 57.71 (7)° in mol-ecule A and 44.95 (7)° in mol-ecule B. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and I⋯O contacts [I⋯O = 3.3646 (15) and 3.2354 (14) Å], forming a three--dimensional network.
منابع مشابه
5-Cyclohexyl-2-(4-fluorophenyl)-3-isopropylsulfonyl-1-benzofuran
In the title compound, C(23)H(25)FO(2)S, the cyclo-hexyl ring adopts a chair conformation. The 4-fluoro-phenyl ring makes a dihedral angle of 50.74 (4)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by inter-molecular C-H⋯π inter-actions.
متن کامل5-Cyclopentyl-2-(4-fluorophenyl)-3-isopropylsulfonyl-1-benzofuran
In the title compound, C22H23FO3S, the cyclo-pentyl ring adopts an envelope conformation with the flap atom connected to the benzofuran residue. The 4-fluoro-phenyl ring makes a dihedral angle of 43.67 (3)° with the mean plane [r.m.s. deviation = 0.008 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions, forming a three--dimensional net...
متن کامل3-Ethylsulfinyl-2-(4-fluorophenyl)-5-iodo-7-methyl-1-benzofuran
In the title compound, C(17)H(14)FIO(2)S, the 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by the dihedral angle of 15.60 (6)°. The crystal structure exhibits an I⋯O inter-action [3.052 (2) Å].
متن کامل2-(4-Fluorophenyl)-5-iodo-3-isopropylsulfinyl-1-benzofuran
In the title compound, C(17)H(14)FIO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 18.88 (9)° with the mean plane of the benzofuran ring. In the crystal, pairs of inter-molecular I⋯O contacts [3.153 (2) Å] link the mol-ecules into inversion dimers.
متن کامل3-[(4-Fluorophenyl)sulfonyl]-5-iodo-2-methyl-1-benzofuran
In the title compound, C(15)H(10)FIO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 72.27 (6)° with the mean plane of the benzofuran fragment [mean deviation of 0.014 (2) Å from the plane defined by the nine constituent atoms]. In the crystal, pairs of weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers, which are further linked via an aromatic π-π...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012